Mobius π-conjugation in cyclic molecules leads to the reversal of Huckel aromaticity rules and affects the electronic and magnetic properties of these systems. We found the first example of a medium-sized macrocyclic structure that is sufficiently flexible to switch between three distinct π-conjugation topologies, planar (T0), Mobius (T1), and twisted Huckel (T2), without changing its oxidation level. Via.
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-moi reblogged this from proofmathisbeautiful and added:
oh wow nice..this would be why i don’t totally hate structural chemistry. awesomeness
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